What is the ruling on me wearing tight or sleeveless blouses in front of a discerning boy who has not reached puberty? Is my 'awrah with him the same as my 'awrah in front of women? And what is the solution if it is not permissible to wear them in front of him at a wedding, and how can I convince my mother of that?

If the brother has reached the age of sexual desire, he is to be treated as an adult. If your clothes are very tight, revealing the 'awrah (intimate parts) and causing temptation, then it is not permissible for you to appear before him or before other mahrams (unmarriageable kin) while wearing them. In this situation, gently and respectfully explain to your mother the limits of a woman's 'awrah before mahrams, while being careful to honor her and treat her kindly.